PREPARATION OF Al-Sc ALLOY IN CHLORIDE SYSTEM WITH MOLTEN SALT ELECTROLYSIS

Tian Yanwen, Sun Benliang and Zhai Yuchun
School of Materials &
Metallurgy, Northeastern University, Shenyang 110006, P.R.China

ABSTRACT

NaCl-KCl(equimolar)-ScCl3 system was chosen as the electrolyte, 3-factor quadratic common rotation combination orthogonal design was employed to investigate the effects of temperature, t, current density, J, and the content of ScCl3 in the molten salt, w(ScCl3), on the content of Sc in the Al-Sc alloys, w(Sc), and the current efficiency, ¦ÇI, in the preparation of Al-Sc alloy with molten salt electrolysis. The regression functions of the relationships of w(Sc) and ¦ÇI with t, J and w(ScCl3) were set up. Under the conditions chosen in the experiments, w(Sc) and ¦ÇI can reach about 8% and 85% respectively.

Key words     Al-Sc Alloy    NaCl-KCl(equimolar)-ScCl3 system    molten salt electrolysis


Project 59474011 supported by the National Natural Science Foundation of China
Received Jul. 15 , 1997; accepted May 21, 1998